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The Pan de Azúcar volcanic dome complex is a small dacitic center, erupted during the Middle Miocene in the southern portion of the Laguna de Pozuelos basin (northern Puna). The complex is associated with Ag-Pb-Zn±Sn mineralization, being part of a regionally extended group of similar magmatic features in the Central Andean Plateau. The eruptive activity in the Pan de Azucar complex comprised three cycles, with emissions from multiple vents linked by a ring fracture. The first cycle involved a plinian phase followed by a pelean event, both located on the northern edge of the complex. Violent explosions, caused by magma degassing, were followed by quieter lava eruptions, whose products were later destroyed by successive gravitational collapses. The second episode, hydromagmatic-vulcanian, occurred mainly in the central section, where hydromagmatic explosions -apparently directed to the west- generated surges, pyroclastic flows and minor fall-out deposits. Biotitic dacite domes and a subvolcanic stock (cerro Mina) were emplaced afterwards. The circulation of water around a progressively cooling magma chamber formed an epithermal system, causing alteration and mineralization of earlier deposits. The absence of hydrothermal alteration in rocks of the third cycle suggests that the epithermal event pre-dated it. The third cycle was mainly of pelean type and consisted of the explosive reactivation (hydromagmatic) of the system, and the shifting of the activity to the southern edge of the complex (cerro Negro) along the ring fracture. The vent was probably occupied by a banded, volatile-rich lava dome, later destroyed by an eruption of pelean s.s. type. Finally, the newly degassed magma erupted as biotitic-hornblendiferous dacite lava domes. The lithostratigraphical and petrographical guides used here to define the dominant subaerial origin of Pan de Azucar could be used to interpret the origin of similar magmatic features, either in Puna or other ancient volcanic terranes. The appropriate definition of such centres should have direct implications for prospecting, exploration and understanding of the ore deposits commonly related to them.
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